Modified plastic



Jan. 2, 1945. P. J. GAYLOR MODIFIED PLASTIC Filed Jan. 20, 1942 N I .NBN

MQ@ Nuvwmw \W m, \N @ETSU Patented Jan. 2, 1945 2,366,514 MODIFIED .PLASTIC Peterl Gaylor, Union, N. J., assignor to Standard 1 Oil Development Company, a corporation of Delaware Application January zo, 1942, serial No. 421,458

(c1. is-ss) 4 4 Claims.

` jThis invention deals with the'production of modified plastics by coating them With a Very thin film of glass. f

Glass possesses Va number of unusual desirable 4properties not `enjoyed by other plastics. It is hard, diicult' to scuff or scratch, and is chemically inert towards most reagents. Unfortunately, however, it shatters very readily due to its extreme brittleness, and for this reason it is still classed as an extremely perishable material. Furthermore, in the forms generally used, glass is not very exible. l

Organic plastics, on the other hand, are quite ilexible in thick sheets and are not subject to shattering since they usually are not brittle. However, they do possess the property of ready scufling or scratching because ofv their relative softness, and they are also subject to deteriora-- tion by oxidation, light, and numerous chemical reagents.

' The shattering power of glass has, to some extent, been overcome in the prior art by sandwiching alternate layers of thin sheets of yplastic between thick sheets of glass. Bullet-proof glass has been made in this manner, but such a technique'has not resulted in any improvement in molded plastic products or flexible sheets, and large glass windows, prepared in this manner, still collapse due tothe large proportion of fragile glass present and the high density of the composil tions.

The present invention deals with the production of light weight extremely flexible composi# tions capable of numerous useful adaptations. It essentially comprises coating of the surface of a relatively thick piece of organic plastic with an extremely thin sheet of an inorganic plastic such as glass or similar metal silicates.

When present in thick sheets, say of about ove:` 0.01" thickness, glass is a very fragile, brittle and inflexible material. But, when drawn out in thin sheets of less than 0.01" or even less than 0.001", glass is quite exible and can be twisted cold in the shape of tubes of fairly small diameter without fracturing. Such lms are still very fragile and brittle, and hole may be readily poked through the surface with the slightest amount oi eliort. However, when these films are supported uniformly by a relatively thick', solid, somewhat flexible organic plastic backing. they approach more nearly a sort of monolithic structure, and lose most of their fragile propensities. In this form, such compositions offer a number of advantages over plastics produced in the present art. and serve new and useful purposes. l It is possible.

for example, to prepare plastic window shades fmade of a relatively thick sheet of plastic such as plastlcized polyvinyl chloride or vinyl chloride-` acetate-copolym'er coated on either side with a very thin sheet of glass, cemented evenly on the surface thereof which, for all practical purposes,

might be called fexible glass shades since they are not affected by light or the atmosphere, and may be cleaned by wiping the glass surfaces with a moist cloth. Furthermore,` such shades are more durable because the glass layer prevents continuous volatilization of the plasticizer which is usually the cause of gradual embrittlement` of such plastics on aging. y

Glass pipes employed in industry are limitedl as to uses mainly because they are readily broken.

By means of the. present inventionfit is possible to produce flexible pipes serving the same purpose. A pipe constructed of plastic is merely coated on the insi'de 4(or outside ifV desiredl with a very thin flexible sheet of glass. This sheet is preferably applied after the surface of the plastic pipe is coated with a cement. The glass sheet is then smoothed over the cemented surface so that a solid backing is obtained. y A suitable cement for this purpose may be a lower molecular weight polymer of the plastic from which the bodyof the I pipe is manufactured, or it may be a` polyisobutene polymer, alkyl and/or aryl silicone polymers, low molecular weight polystyrene, polyacrylate or methacrylate, polyvinyl acetals, and j thelike.

Molded rplastic products may be coated with a thin glass sheet in the 4same manner, thereby obtaining a glossy, reproof, scratchproof surface which protects the plastic from light and oxidation. The glass may be colored so as to eliminate the necessity of coloring the plastic. Furthermore, the color will not fade or change in hue as in the case ofthe usual plastic colors, Optical lenses may be treated in a like manner, since the main difficulties with plastic lenses now are their scratching and scufng properties` .Window glass may also be made in the same manner, and such windows are more permanent and more diiiiult to break into. Venetian blinds and similar objects may be prepared in a like manner;

Plastics which may be treated in this manner are any of the polymer or resin or even rubber products such as phenol formaldehyde, methacrylate, vacrylate, styrene, urea-aldehyde, vinyl chloride-acetate, polyacetate vinylidene chloride, nylon type acid amide, ethylene, unsaturated ketone and/or'ether, diole'ln, iso-olefin and other polymeric substances and copolymers thereof.

V Heating of the plastic surface by this means is The glassnlm may be attached tothe surface lby y,

melting the surface by a flame or other means and applying the glass film with a roller or press.

Difference vin coefficient of expansion due' to termed as glasses in inorganic chemistry, these being devoid of carbon in their molecular struc ture.

A translucent effect can be obtained by matting thin glass fibers upon a cementing surface of a plastic, although, as might be expected, .a large part of 'the plastic surface is still exposed, and hence this method is not as eiective in protecting the. surfaceof the plastic as the other methods employing a continuous thin flexible form of glass.

Referring to the 'accompanying drawing, Fig. I is a diagrammatic representation of .one mode of carrying out the present invention; Fig. II shows one type ofv finished product made according to the present invention. In the drawing, numeral I indicatesa fiat metal surface such as a at steel table, .upon which is placed a sheet of plastic material, as for example, polystyrene, polymethacrylate, vinylidene chloride copolymer, etc. Numeral 3 represents a previously prepared thin ilmsof glass f-ed to the table by soft rubber rollers 4. The plastic is heated by flame 5, the fuel for which is supplied through line 6.

carried out only to an extent suillcient to soften 'the surface of the plastic sheet upon which is impressed the heated glass film by soft rubber, asbestos or other type roller 1 which is moved along the table guide by a. forward movement of the arm 8. 'Ihe movements of burner 5 and roller 1 are synchronized by the connecting arm 9. By thisl means a firmly adherent glass film rcoated plastic sheet is obtained.

I claim:

1. A composition of matter comprising a relatively thick cross-section-of solidorganic plastic, and a relatively thin flexible lm of glass cemented on at least a portion of the exposed plastic, thereby protecting the exposed suriacerof the plastic.

2. A composition of matter comprising a molded object of solid organic plastic, the exposed surface of which is at least partially coated with a firmly adhering ilexible lm of solid inorganic plastic of greater hardness'than the organic plastic.

. 3. A composition of matter comprising a ilexible solidorganic plastic of relatively thick crosssection, the exposed surface of which is at least partially. coated with an adherent thin flexible film of glass.

4. A method of producing modified plastics Y comprising producing an object of organic plasltic of relatively thick .cross-section, applying to at least -a portion of the exposed surface thereof a thin firmly adherent flexible film of glass and applying a slight pressure to the outer sur face of the film to insure' satisfactory adhesion.

PETER J. GAYLOR. 

